in reply to Mac Addresses
arpwatch doesn't run on windows, but if you have other boxen on your network, it might be of use to you.
(note: IP has been inferred from your question, but not stated. Windows has been inferred, though the OS running on the PCs is also unstated.)
arping also has a dependency of unix or unix-like OS.
Both tools provides output that predictable and therefore easily parsed by perl.
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