in reply to Starting with Perl 6
1. I've been sort of building up to starting to write on a perldoc analog for Perl 6. You can read about it here. However, it's still only just in the late planning stage, with no actual documentation.
2. The Perl 6 Advent Calendar, as well as Moritz's excellent Perl 5 to 6 posts.
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Seekers of Perl Wisdom