You're almost there! Try the following:
use strict;
use warnings;
my $abc = <<END;
The following ABB products and versions are affected:
• ABB Interlink Module: Versions 4.6 through 4.9
• IRC5 OPC Server: Versions up to and including 5.14.01
• PC SDK: Versions up to and including 5.14.01
• PickMaster 3: Versions up to and including 3.3
• PickMaster 5: Versions up to and including 5.13
• Robot Communications Runtime: Versions up to and including 5.14.01
• RobotStudio: Versions supporting IRC5 up to and including 5.14.01
• RobView 5: Works together with other products listed here.
• WebWare SDK: Versions 4.6 through 4.9
• WebWare Server: Versions 4.6 through 4.91
END
print "$1\n" if $abc =~ /(?:PickMaster 3:\s+)([^\n]+)/s;
Output:
Versions up to and including 3.3