Volume[@VolumeCategory="L"]
relative to the root of the document (
/) means
/Volume[@VolumeCategory="L"]
They fail to find a match since there's no element named Volume at the root of the document.
/root/Volume[@VolumeCategory="L"]
would find the node in question, and so would its relative equivalent
root/Volume[@VolumeCategory="L"]
It's just like directories.
$ cd /
$ ls -d ikegami
ls: cannot access ikegami: No such file or directory
$ ls -d /ikegami
ls: cannot access /ikegami: No such file or directory
$ ls -d /home/ikegami
/home/ikegami
$ ls -d home/ikegami
home/ikegami