Hi,
Use this below code
#!/usr/local/bin/perl
use strict;
use warnings;
use XML::Simple qw/:strict/;
use Data::Dumper;
my $xml = qq{
<InteractionComponentList>
<InteractionComponent role_type="input" molecule_idref="200568"></Inte
+ractionComponent></InteractionComponentList>};
my $xml_simple = XML::Simple->new(KeyAttr => 1, KeepRoot => 1, ForceAr
+ray => 1);
my $output = $xml_simple->XMLin($xml);
my %hash = %{$output->{InteractionComponentList}[0]{InteractionCompone
+nt}[0]};
print Dumper(\%hash);