|The stupid question is the question not asked|
So, basically the file you are trying to delete does not exist. Why do you think that is? (Hint: what do you see when you print $file within the loop?)
Your problem is that readdir returns the names of the files; not their full paths, so what your code is trying to do is delete a filename read from a path on your V: drive, from your current directory.
Something like this might work:
And for future reference, investigate glob which makes doing this sort of thing much easier.
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In reply to Re^3: remove files from the V volume on windows