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November 18, 2004 13:41 WSPC/140-IJMPB

02639

International Journal of Modern Physics B

Vol. 18, Nos. 23 & 24 (2004) 3227–3266

c World Scientific Publishing Company

BOUND AND SCATTERING STATES OF ITINERANT CHARGE

CARRIERS IN COMPLEX MAGNETIC MATERIALS

A. L. KUZEMSKY

Bogoliubov Laboratory of Theoretical Physics, Joint Institute for Nuclear Research,

141980 Dubna, Moscow Region, Russia

kuzemsky@thsun1.jinr.ru

Received 12 October 2004

The concept of magnetic polaron is analyzed and developed to elucidate the nature of

itinerant charge carrier states in magnetic semiconductors and similar complex magnetic

materials. By contrasting the scattering and bound states of carriers within the s–d exchange model, the nature of bound states at finite temperatures is clarified. The free

magnetic polaron at certain conditions is realized as a bound state of the carrier (electron or hole) with the spin wave. Quite generally, a self-consistent theory of a magnetic

polaron is formulated within a nonperturbative many-body approach, the Irreducible

Green Functions (IGF) method which is used to describe the quasiparticle many-body

dynamics at finite temperatures. Within the above many-body approach we elaborate

a self-consistent picture of dynamic behavior of two interacting subsystems, the localized spins and the itinerant charge carriers. In particular, we show that the relevant

generalized mean fields emerges naturally within our formalism. At the same time, the

correct separation of elastic scattering corrections permits one to consider the damping

effects (inelastic scattering corrections) in the unified and coherent fashion. The damping

of magnetic polaron state, which is quite different from the damping of the scattering

states, finds a natural interpretation within the present self-consistent scheme.

Keywords: Spin-fermion model; itinerant charge carriers; bound and scattering states;

magnetic polaron.

1. Introduction

The properties of itinerant charge carriers in complex magnetic materials are at

the present time of much interest. The magnetic polaron problem is of particular

interest because one can study how a magnetic ion subsystem influences electronic

properties of complex magnetic materials. Recently, semiconducting ferro- and antiferromagnetic compounds have been studied very extensively.1 – 5 Substances which

we refer to as magnetic semiconductors, occupy an intermediate position between

magnetic metals and magnetic dielectrics. Magnetic semiconductors are characterized by the existence of two well defined subsystems, the system of magnetic

moments which are localized at lattice sites, and a band of itinerant or conduction

carriers (conduction electrons or holes). Typical examples are the Eu-chalcogenides,

3227

November 18, 2004 13:41 WSPC/140-IJMPB

3228

02639

A. L. Kuzemsky

where the local moments arise from 4f electrons of the Eu ion, and the spinell

chalcogenides containing Cr 3+ as a magnetic ion. There is experimental evidence

of a substantial mutual influence of spin and charge subsystems in these compounds.

This is possible due to the sp–d(f ) exchange interaction of the localized spins and

itinerant charge carriers. An itinerant carrier perturbs the magnetic lattice and

is perturbed by the spin waves. It was shown that the effects of the sp–d or s–f

exchange,6 – 10 as well as the sp–d(f ) hybridization,11 the electron-phonon interaction and disorder effects contributed to essential physics of these compounds and

various anomalous properties are found. In these phenomena, the itinerant charge

carriers play an important role and many of these anomalous properties may be attributed to the sp–d(f ) exchange interaction.10,12 As a result, an electron travelling

through a ferromagnetic crystal will in general couple to the magnetic subsystem.

From the quantum mechanics point of view this means that the wave function of

the electron would depend not only upon the electron coordinate but upon the state

of the spin system as well. Recently, further attempts have been made to study and

exploit carriers which are exchange-coupled to the localized spins.13 – 17 The effect

of carriers on the magnetic ordering temperature is now found to be very strong

in diluted magnetic semiconductors (DMS).4,13 Diluted magnetic semiconductors

are mixed crystals in which magnetic ions (usually M n++ ) are incorporated in a

substitutional position of the host (typically a II-VI or III-V) crystal lattice. The

diluted magnetic semiconductors offer a unique possibility for a gradual change of

the magnitude and sign of exchange interaction by means of technological control

of carrier concentration and band parameters.

It was Kasuya8,10,18– 20 who first clarified that the s–f interaction works differently in magnetic semiconductors and in metals.21 The effects of the sp–d(f )

exchange on the ferromagnetic state of a magnetic semiconductor were discussed

in Refs. 22–26. It was shown that the effects of the sp–d(f ) exchange interaction are of a more variety in the magnetic semiconductors10 than in the magnetic

metals,21 because in the former there are more parameters which can change over

wide ranges.10,18 – 20 The state of itinerant charge carriers may be greatly modified

due to the scattering on the localized spins.27 – 30 Interaction with the subsystem

of localized spins leads to renormalization of bare states and the scattering and

bound state regimes may occur.31,32 Along with the scattering states, an additional

dressing effect due to the sp–d(f ) exchange interaction can exist in some of these

materials.29,33,34 To some extent, the interaction of an itinerant carrier in a ferromagnet with spin waves is analogous to the polaron problem in polar crystals if we

can consider the electron and spin waves to be separate subsystems.22 Note, however, that the magnetic polaron differs from the ordinary polaron in a few important

points.25,26,34 – 36

To describe this situation a careful analysis of the state of itinerant carriers

in complex magnetic materials37 is highly desirable. For this aim a few model

approaches have been proposed. A basic model is a combined spin-fermion model

(SFM) which includes interacting spin and charge subsystems.25,27,38 – 40

November 18, 2004 13:41 WSPC/140-IJMPB

02639

Bound and Scattering States in Magnetic Materials

3229

The problem of adequate physical description of itinerant carriers (including

a self-trapped state) within various types of generalized spin-fermion models has

intensively been studied during the last decades.27,39 – 42 The dynamic interaction

of an itinerant electron with the spin-wave system in a magnet has been studied by

many authors,8,10,22,25 including the effects of external fields. It was shown within

the perturbation theory that the state of an itinerant charge carrier is renormalized due to the spin disorder scattering. The second order perturbation treatment

leads to the lifetime of conduction electron and explains qualitatively the anomalous temperature dependence of the electrical resistivity.43,44,31,32,25 The polaron

formation in the concentrated systems leads to giant magneto-resistive effects in

the Eu chalcogenides.1,33

The concept of magnetic polaron in the magnetic material was discussed

and analyzed in Refs. 33, 38, 45, 25, 26. The future development of this concept was stimulated by many experimental results and observations on magnetic

semiconductors.3,46 – 48 A paramagnetic polaron in magnetic semiconductors was

studied by Kasuya,25 who argued on the basis of thermodynamics, that once electron is trapped into the spin cluster, the spin alignment within the spin cluster

increases and thus the potential to trap an electron increases. The bound states

around impurity ions of opposite charge and self-trapped carriers were discussed by

de Gennes.41 Emin34 defined the self-trapped state and formulated that

“the unit comprising the self-trapped carrier and the associated atomic

deformation pattern is referred to as a polaron, with the adjective small

or large denoting whether the spatial extent of the wave function of the

self-trapped carrier is small or large compared with the dimensions of a

unit cell”.

In papers [Refs. 45, 49–52], a set of self-consistent equations for the self-trapped

(magnetic polaron) state was derived and it was shown that the paramagnetic

polaron appeared discontinuously with decreasing temperature. These studies were

carried out for wide band materials and the thermodynamic arguments were mainly

used in order to determine a stable configuration. Some specific points of spinpolaron and exiton magnetic polaron were discussed further in papers [Refs. 52–56].

Properties of the magnetic polaron in a paramagnetic semiconductor were studied by Yanase,57 Kubler58 and by Auslender and Katsnelson.59 The later authors60

developed a detailed theory of the states of itinerant charge carriers in ferromagnetic semiconductors in the spin-wave (low temperature) region within the framework of variational approach. The effect of the electron-phonon interaction on the

self-trapped magnetic polaron state was investigated by Umehara.61,62 A theory

for self-trapped magnetic polaron in ferromagnetic semiconductor with a narrow

band was formulated by Takeda and Kasuya.63 The electron crystallization in

antiferromagnetic semiconductors was studied by Umehara,64,65 and a dense magnetic polaron state was conjectured to describe the physics of Gd3−x vS4 .

November 18, 2004 13:41 WSPC/140-IJMPB

3230

02639

A. L. Kuzemsky

A model of the bound magnetic polaron, i.e. electron trapped on impurity or

by vacancy48 was developed in papers [Refs. 66, 67]. The general thermodynamic

model of the bound magnetic polaron and its stability was considered in Refs. 68–70.

Then similar models were studied by several authors.3,71,72

The state of a conduction electron in a ferromagnetic crystal (magnetic polaron)

was investigated by Richmond73 who deduced an expression for one-electron Green

function. Shastry and Mattis74 presented a detailed analysis of the one-electron

Green function at zero temperature. They constructed an exact Green function for

a single electron in a ferromagnetic semiconductor and highlighted the crucial differences between bound- and scattering-state contributions to the electron spectral

weight. A finite temperature self-consistent theory of magnetic polaron within the

Green functions approach was developed in Ref. 75.

Recently, new interest in the problem of magnetic polaron was stimulated by the

studies of magnetic and transport properties of the low-density carrier ferromagnets, diluted magnetic semiconductors (DMS).76 – 78,4,5 The concept of the magnetic

polaron, the self-trapped state of a carrier and spin wave, attracts increasing attention because of the anomalous magnetic, transport, and optical properties of

DMS77,79 – 83 and the perovskite manganites.37,84,85 For example, a two-component

phenomenological model, describing polaron formation in colossal magnetoresistive

compounds, has been devised recently.86 The paper [Ref. 78] includes a detailed

analysis of the polaron-polaron interaction effects in DMS.

The purpose of the present work is to elucidate further the nature of itinerant

carrier states in magnetic semiconductors and similar complex magnetic materials.

An added motivation for performing new consideration and a careful analysis of

the magnetic polaron problem arise from the circumstance that the various new

materials were fabricated and tested, and a lot of new experimental facts were

accumulated. This paper deals with the effects of the local exchange due to interaction of carrier spins with the ionic spins or the sp–d or s–f exchange interaction

on the state of itinerant charge carriers. We develop in some detail a many-body

approach to the calculation of the quasiparticle energy spectra of itinerant

carriers so as to understand their quasiparticle many-body dynamics. The concept of the magnetic polaron is reconsidered and developed and the scattering and

bound states are thoroughly analyzed. In the previous papers, we set up the formalism of the method of Irreducible Green Functions (IGF).87 This IGF method allows

one to describe quasiparticle spectra with damping for many-particle systems on a

lattice with complex spectra and a strong correlation in a very general and natural

way. This scheme differs from the traditional method of decoupling of an infinite

chain of equations88 and permits a construction of the relevant dynamic solutions

in a self-consistent way at the level of the Dyson equation without decoupling the

chain of equations of motion for the GFs.

In this paper, we apply the IGF formalism to consider quasiparticle spectra of

charge carriers for the lattice spin-fermion model consisting of two interacting subsystems. The concepts of magnetic polaron and the scattering and bound states are

November 18, 2004 13:41 WSPC/140-IJMPB

02639

Bound and Scattering States in Magnetic Materials

3231

analyzed and developed in some detail. We consider thoroughly a self-consistent

calculation of quasiparticle energy spectra of the itinerant carriers. We are particularly interested in how the scattering state appears differently from the bound state

in magnetic semiconductor.

The key problem of most of this work is the formation of magnetic polaron under

various conditions on the parameters of the spin-fermion model. It is the purpose

of this paper to explore more fully the effects of the sp–d(f ) exchange interaction

on the state of itinerant charge carriers in magnetic semiconductors and similar

complex magnetic materials.

2. The Spin-Fermion Model

The concept of the sp–d (or d–f ) model plays an important role in the quantum

theory of magnetism.9,10,18,12,40 In this section, we consider the generalized sp–d

model which describes the localized 3d(4f )-spins interacting with s(p)-like conduction (itinerant) electrons (or holes) and takes into consideration the electronelectron interaction.

The total Hamiltonian of the model (for simplicity we shall call it the s–d model)

is given by

H = Hs + Hs−d + Hd .

(1)

The Hamiltonian of band electrons (or holes) is given by

Hs =

XX

ij

tij a†iσ ajσ +

σ

1X

U niσ ni−σ .

2 iσ

(2)

This is the Hubbard model. We adopt the notation

X

X †

~ i ) , a† = N −1/2

~ i) .

aiσ = N −1/2

akσ exp(i~k R

akσ exp(−i~kR

iσ

~

k

~

k

In the case of a pure semiconductor, at low temperatures the conduction electron

band is empty and the Coulomb term U is therefore not so important. A partial

occupation of the band leads to an increase in the role of the Coulomb correlation. It is clear that we treat conduction electrons as s-electrons in the Wannier

representation. In doped DMS the carrier system is the valence band p-holes.

The band energy of Bloch electrons ~k is defined as follows:

X

~i − R

~ j )] ,

tij = N −1

~k exp[i~k(R

~

k

where N is the number of lattice sites. For the tight-binding electrons in a cubic

lattice we use the standard expression for the dispersion

X

~k = 2

t(~aα ) cos(~k~aα )

(3)

α

November 18, 2004 13:41 WSPC/140-IJMPB

3232

02639

A. L. Kuzemsky

where ~aα denotes the lattice vectors in a simple lattice with the inversion centre.

The term Hs−d describes the interaction of the total 3d(4f )-spin with the spin

density of the itinerant carriers11

XX

X

−σ †

z

~i = −IN −1/2

[S−q

akσ ak+q−σ + zσ S−q

a†kσ ak+qσ ]

(4)

I~σi S

Hs−d = −2

i

σ

kq

where sign factor zσ is given by

zσ = (+, −) for σ = (↑, ↓)

and

−σ

S−q

=

(

−

S−q

if σ = +

+

S−q

if σ = −

.

For example, in DMS4 the local exchange coupling resulted from the p–d hybridiza2

tion between the Mn d levels and the p valence band I ∼ Vp−d

. In magnetic semiconductors this interaction can lead to the formation of the bound electron-magnon

(polaron-like) bound state due to the effective attraction of the electron and magnon

in the case of antiferromagnetic coupling (I < 0).

For the subsystem of localized spins we have

X

1X

~i S

~j = − 1

~q S

~−q .

Jij S

Jq S

(5)

Hd = −

2 ij

2 q

Here we use the notation

X

~ i) ,

Siα = N −1/2

Skα exp(i~kR

Skα = N −1/2

~

k

X

~ i)

Siα exp(−i~kR

~i

2

1

±

z

∓ Sk+q

, [Sk+ , Sq− ] = 1/2 Sk+q

N 1/2

N

X

~i − R

~ j )] .

Jij = N −1

J~k exp[i~k(R

[Sk± , Sqz ] =

~

k

This term describes a direct exchange interaction between the localized 3d(4f ) magnetic moments at the lattice sites i and j. In the DMS system this interaction is

rather small. The ferromagnetic interaction between the local moments is mediated

by the real itinerant carriers in the valence band of the host semiconductor material. The carrier polarization produces the RKKY exchange interaction of local

moments7,8,21,12

X

~i S

~j .

HRKKY = −

Kij S

(6)

i6=j

2

4

Vp−d

.

We emphasize that Kij ∼ |I | ∼

To explain this, let us remind that the

microscopic model,11 which contains basic physics, is the Anderson–Kondo model12

XX

XX

H=

tij a†iσ ajσ − V

(a+

iσ djσ + h.c.)

ij

σ

− Ed

ij

XX

i

σ

ndiσ +

σ

1X

U ndiσ ndi−σ .

2 iσ

(7)

November 18, 2004 13:41 WSPC/140-IJMPB

02639

Bound and Scattering States in Magnetic Materials

3233

For the symmetric case U = 2Ed and for U V Eq. (7) can be mapped onto the

Kondo lattice model12 (KLM)

XX

X

~i .

H=

tij a†iσ ajσ −

2I~σi S

(8)

ij

σ

i

4V 2

Ed .

The KLM may be viewed as the low-energy sector of the initial

Here I ∼

model Eq. (7).

We follow the previous treatments and take as our model Hamiltonian expression (1). For the sake of brevity we omit in this paper the U-term (lowconcentration limit). This U-term can be included into consideration straightforwardly (see Ref. 40). As stated above, the model will represent an assembly of

itinerant charge carriers in a periodic atomic lattice. The carriers are represented

by quantized Fermi operators. The lattice sites are occupied by the localized spins.

Thus, this model can really be called the spin-fermion model.

3. Outline of the IGF Method

In this section, we discuss the main ideas of the IGF approach that allows one to

describe completely quasiparticle spectra with damping in a very natural way.

We reformulated the two-time GF method87 to the form which is especially

adjusted to correlated fermion systems on a lattice and systems with complex spectra. A very important concept of the whole method is the Generalized Mean Fields

(GMFs), as it was formulated in Ref. 87. These GMFs have a complicated structure for a strongly correlated case and complex spectra, and are not reduced to the

functional of mean densities of the electrons or spins when one calculates excitation

spectra at finite temperatures.

To clarify the foregoing, let us consider a retarded GF of the form88

Gr = hhA(t), A† (t0 )ii = −iθ(t − t0 )h[A(t)A† (t0 )]η i ,

η = ±.

(9)

As an introduction to the concept of IGFs, let us describe the main ideas of this

approach in a symbolic and simplified form. To calculate the retarded GF G(t − t0 ),

let us write down the equation of motion for it

ωG(ω) = h[A, A† ]η i + hh[A, H]− |A† iiω .

(10)

Here we use the notation hhA(t), A† (t0 )ii for the time-dependent GF and hhA|A† iiω

for its Fourier transform.88 The notation [A, B]η refers to commutation and anticommutation depending on the value of η = ±.

The essence of the method is as follows87 :

It is based on the notion of the “IRREDUCIBLE” parts of GFs (or the irreducible parts of the operators, A and A† , out of which the GF is constructed) in

terms of which it is possible, without recourse to a truncation of the hierarchy of

equations for the GFs, to write down the exact Dyson equation and to obtain an exact analytic representation for the self-energy operator. By definition, we introduce

the irreducible part (ir) of the GF

(ir)

hh[A, H]− |A† ii = hh[A, H]− − zA|A† ii .

(11)

November 18, 2004 13:41 WSPC/140-IJMPB

3234

02639

A. L. Kuzemsky

The unknown constant z is defined by the condition (or constraint)

(ir)

h[[A, H]− , A† ]η i = 0

(12)

which is an analogue of the orthogonality condition in the Mori formalism. Let us

emphasize that due to the complete equivalence of the definition of the irreducible

parts for the GFs ((ir) hh[A, H]− |A† ii) and operators ((ir) [A, H]− ) ≡ ([A, H]− )(ir)

we will use both the notation freely ((ir) hhA|Bii is the same as hh(A)(ir) |Bii). A

choice one notation over another is determined by the brevity and clarity of notation

only. From the condition (12) one can find

z=

h[[A, H]− , A† ]η i

M1

=

.

h[A, A† ]η i

M0

(13)

Here M0 and M1 are the zeroth and first order moments of the spectral density.

Therefore, the irreducible GFs are defined so that they cannot be reduced to the

lower-order ones by any kind of decoupling. It is worth noting that the term “irreducible” in a group theory means a representation of a symmetry operation that

cannot be expressed in terms of lower dimensional representations. Irreducible (or

connected) correlation functions are known in statistical mechanics. In the diagrammatic approach, the irreducible vertices are defined as graphs that do not contain

inner parts connected by the G0 -line. With the aid of the definition (11) these concepts are expressed in terms of retarded and advanced GFs. The procedure extracts

all relevant (for the problem under consideration) mean-field contributions and puts

them into the generalized mean-field GF which is defined here as

G0 (ω) =

h[A, A† ]η i

.

(ω − z)

(14)

To calculate the IGF (ir) hh[A, H]− (t), A† (t0 )ii in (10), we have to write the equation

of motion for it after differentiation with respect to the second time variable t0 . The

condition of orthogonality (12) removes the inhomogeneous term from this equation

and is a very crucial point of the whole approach. If one introduces the irreducible

part for the right-hand side operator, as discussed above for the “left” operator,

the equation of motion (10) can be exactly rewritten in the following form:

G = G 0 + G 0 P G0 .

(15)

The scattering operator P is given by

P = (M0 )−1 ((ir) hh[A, H]− |[A† , H]− ii(ir) )(M0 )−1 .

(16)

The structure of Eq. (16) enables us to determine the self-energy operator M by

analogy with the diagram technique

P = M + M G0 P .

(17)

We use here the notation M for self-energy (mass operator in quantum field theory).

From the definition (17) it follows that the self-energy operator M is defined as a

proper (in the diagrammatic language, “connected”) part of the scattering operator

November 18, 2004 13:41 WSPC/140-IJMPB

02639

Bound and Scattering States in Magnetic Materials

3235

M = (P )p . As a result, we obtain the exact Dyson equation for the thermodynamic

double-time Green functions

G = G 0 + G0 M G .

(18)

The difference between P and M can be regarded as two different solutions of two

integral equations (15) and (18). However, from the Dyson equation (18) only the

full GF is seen to be expressed as a formal solution of the form

G = [(G0 )−1 − M ]−1 .

(19)

Equation (19) can be regarded as an alternative form of the Dyson equation (18) and

the definition of M provides that the generalized mean-field GF G0 is specified. On

the contrary, for the scattering operator P , instead of the property G0 G−1 +G0 M =

1, one has the property

(G0 )−1 − G−1 = P G0 G−1 .

Thus, the very functional form of the formal solution (19) precisely determines the

difference between P and M .

Thus, by introducing irreducible parts of GF (or irreducible parts of the operators, out of which the GF is constructed) the equation of motion (10) for the GF

can exactly be (but using the orthogonality constraint (12)) transformed into the

Dyson equation for the double-time thermal GF (18). This result is very remarkable

because the traditional form of the GF method does not include this point. Notice

that all quantities thus considered are exact. Approximations can be generated not

by truncating the set of coupled equations of motions but by a specific approximation of the functional form of the mass operator M within a self-consistent scheme

expressing M in terms of the initial GF

M ≈ F [G] .

Different approximations are relevant to different physical situations.

The projection operator technique has essentially the same philosophy. But with

using the constraint (12) in our approach we emphasize the fundamental and central

role of the Dyson equation for calculation of single-particle properties of many-body

systems. The problem of reducing the whole hierarchy of equations involving higherorder GFs by a coupled nonlinear set of integro-differential equations connecting the

single-particle GF to the self-energy operator is rather nontrivial. A characteristic

feature of these equations is that besides the single-particle GF they involve also

higher-order GF. The irreducible counterparts of the GFs, vertex functions, serve

to identify correctly the self-energy as

−1

M = G−1

.

0 −G

The integral form of the Dyson equation (18) gives M the physical meaning of

a nonlocal and energy-dependent effective single-particle potential. This meaning

can be verified for the exact self-energy using the diagrammatic expansion for the

causal GF.

November 18, 2004 13:41 WSPC/140-IJMPB

3236

02639

A. L. Kuzemsky

It is important to note that for the retarded and advanced GFs, the notion

of the proper part M = (P )p is symbolic in nature.87 In a certain sense, it

is possible to say that it is defined here by analogy with the irreducible manyparticle T -matrix. Furthermore, by analogy with the diagrammatic technique, we

can also introduce the proper part defined as a solution to the integral equation

(17). These analogues allow us to better understand the formal structure of the

Dyson equation for the double-time thermal GF, but only in a symbolic form.

However, because of the identical form of the equations for GFs for all three types

(advanced, retarded, and causal), we can convert our calculations to causal GF

at each stage of calculations and, thereby, confirm the substantiated nature of

definition (17)! We therefore should speak of an analogy of the Dyson equation.

Hereafter, we drop this stipulating, since it does not cause any misunderstanding.

In a sense, the IGF method is a variant of the Gram–Schmidt orthogonalization

procedure.

It should be emphasized that the scheme presented above gives just a general

idea of the IGF method. A more exact explanation why one should not introduce

the approximation already in P , instead of having to work out M , is given below

when working out the application of the method to specific problems.

The general philosophy of the IGF method is in the separation and identification of elastic scattering effects and inelastic ones. This latter point is quite often

underestimated, and both effects are mixed. However, as far as the right definition

of quasi-particle damping is concerned, the separation of elastic and inelastic scattering processes is believed to be crucially important for many-body systems with

complicated spectra and strong interaction.

From a technical point of view, the elastic GMF renormalizations can exhibit

quite a nontrivial structure. To obtain this structure correctly, one should construct

the full GF from the complete algebra of relevant operators and develop a special

projection procedure for higher-order GFs, in accordance with a given algebra. Then

a natural question arises how to select the relevant set of operators {A 1 , A2 , . . . , An }

describing the “relevant degrees of freedom”. The above consideration suggests an

intuitive and heuristic way to the suitable procedure as arising from an infinite

chain of equations of motion (10). Let us consider the column

A1

A2

.

..

An

where

A1 = A ,

A2 = [A, H] ,

A3 = [[A, H], H], . . . , An = [[· · · [A, H] · · · H ] .

| {z }

n

Then the most general possible Green function can be expressed as a matrix

November 18, 2004 13:41 WSPC/140-IJMPB

02639

Bound and Scattering States in Magnetic Materials

ˆ=

G

**

3237

A1

++

A2

† †

.

.. |(A1 A2 · · · A†n )

.

An

This generalized Green function describes the one-, two-, and n-particle dynamics.

The equation of motion for it includes, as a particular case, the Dyson equation

for single-particle Green function, and the Bethe–Salpeter equation which is the

equation of motion for the two-particle Green function and which is an analogue of

the Dyson equation, etc. The corresponding reduced equations should be extracted

from the equation of motion for the generalized GF with the aid of special techniques

such as the projection method and similar techniques. This must be a final goal

towards a real understanding of the true many-body dynamics. At this point, it is

worthwhile to underline that the above discussion is a heuristic scheme only, but

not a straightforward recipe. The specific method of introducing the IGFs depends

on the form of operators An , the type of the Hamiltonian, and conditions of the

problem.

Here a sketchy form of the IGF method is presented. The aim is to introduce the

general scheme and to lay the groundwork for generalizations. We demonstrated in

Ref. 87 that the IGF method is a powerful tool for describing the quasiparticle excitation spectra, allowing a deeper understanding of elastic and inelastic quasiparticle

scattering effects and the corresponding aspects of damping and finite lifetimes. In

the present context, it provides a clear link between the equation-of-motion approach and the diagrammatic methods due to derivation of the Dyson equation.

Moreover, due to the fact that it allows the approximate treatment of the selfenergy effects on a final stage, it yields a systematic way of the construction of

approximate solutions.

4. Charge and Spin Degrees of Freedom

Our attention will be focused on the quasiparticle many-body dynamics of the

s–d model. To describe self-consistently the charge dynamics of the s–d model,

one should take into account the full algebra of relevant operators of the suitable

“charge modes” which are appropriate when the goal is to describe self-consistently

the quasi-particle spectra of two interacting subsystems.

The simplest case is to consider a situation when a single electron is injected into

an otherwise perfectly pure and insulating magnetic semiconductor. The behavior

of charge carriers can be divided into two distinct limits based on interrelation

between the band width W and the exchange interaction I:

|2IS| W ;

|2IS| W .

Exact solution for the s–d model is known only in the strong-coupling limit, where

the band width is small compared to the exchange interaction. This case can be

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A. L. Kuzemsky

considered as a starting point for the description of narrow band materials. The

case of intermediate coupling, when |2IS| ' W , makes serious difficulties.

To understand how the itinerant charge carriers behave in a wide range of

values of model parameters, consider the equations of motion for the charge and

spin variables.

[akσ , Hs ]− = k akσ

X

−σ

z

(S−q

aq+k−σ + zσ S−q

aq+kσ )

[akσ , Hs−d ]− = −IN −1/2

(20)

(21)

q

[Sk+ , Hs−d ]− = −IN −1

−

[S−k

, Hs−d ]− = −IN −1

X

+

z

[2Sk−q

a†p↑ ap+q↓ − Sk−q

(a†p↑ ap+q↑ − a†p↓ ap+q↓ )]

X

−

z

[2Sk−q

a†p↓ ap+q↑ − Sk−q

(a†p↑ ap+q↑ − a†p↓ ap+q↓ )]

(23)

pq

[Skz , Hs−d ]− = −IN −1

X

X

+

−

(Sk−q

a†p↓ ap+q↑ − Sk−q

a†p↑ ap+q↓ )

(24)

pq

[Sk+ , Hd ]− = N −1/2

−

[S−k

, Hs−d ]− = −IN −1

(22)

pq

X

+

z

Jq (Sqz Sk−q

− Sk−q

Sq+ )

(25)

q

−

z

[2Sk−q

a†p↓ ap+q↑ − Sk−q

(a†p↑ ap+q↑ − a†p↓ ap+q↓ )]

(26)

pq

From Eqs. (20)–(26) it follows that the localized spin and itinerant charge variables

are coupled.

We have the following kinds of charge

akσ ,

a†kσ ,

nkσ = a†kσ akσ

and spin operators

Sk+ ,

−

S−k

= (Sk+ )† ,

X †

X †

σk+ =

ak↑ ak+q↓ ; σk− =

ak↓ ak+q↑ .

q

q

There are additional combined operators

X

−σ

z

aq+k−σ + zσ S−q

aq+kσ ) .

bkσ =

(S−q

q

In the lattice (Wannier) representation the operator bkσ reads

biσ = (Si−σ ai−σ + zσ Siz aiσ ) .

(27)

It was clearly shown in Refs. 8, 9, 22, 27, 43 that the calculation of the energy of

itinerant carriers involves the dynamics of the ion spin system. In the approximation

of rigid ion spins,27 i.e.:

Sjx = Sjy = 0 ,

Sjz = S

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Bound and Scattering States in Magnetic Materials

3239

the energy shift of electron was estimated as

σ

S2 X

|Iq |2

∆ε(kσ) ∼ −I S +

.

2

4

(k) − (k − q)

q6=0

The dynamic term was estimated as

∆ε(k ↑)

∼

Z

1

S

|Iq |2 N (ω(q))

S2 X

|IQ |2

+

.

d3 q

3

4

(k) − (k − Q) 2N (2π)

(k) − (k − q) − IhS z i + Dq 2

Q6=0

For the case of rare-earth metals, the electron-magnon interaction in the s–d model

within a second-order perturbation theory was studied by Liu and Davis89 and by

Kim90,91 within the Bogoliubov–Tyablikov88 GFs method.

To describe self-consistently the charge carrier dynamics of the s–d model within

a sophisticated many-body approach, one should take into account the full algebra

of relevant operators of the suitable “modes” (degrees of freedom) which are appropriate when the goal is to describe self-consistently quasiparticle spectra of two

interacting subsystems. An important question in this context is the self-consistent

picture of the quasiparticle many-body dynamics which takes into account the complex structure of the spectra due to the interaction of the “modes”. Since our goal

is to calculate the quasiparticle spectra of the itinerant charge carriers, including

bound carrier-spin states, a suitable algebra of the relevant operators should be constructed. In principle, the complete algebra of the relevant “modes” should include

the spin variables too. The most full relevant set of the operators is

{aiσ , Siz , Si−σ , Siz aiσ , Si−σ ai−σ } .

That means that the corresponding relevant GF for interacting charge and spin

degrees of freedom should have the form

†

†

†

z

σ0

z

σ

hhaiσ |a

hhaiσ |Sj ii

hhaiσ |Sj ii

hhaiσ |a

hhSiz |a

z ii

hhSiz |Sj

σ0 ii

hhSiz |Sj

hhSiz |a

ii

jσ0

†

ii

jσ0

−σ †

|a 0 ii

i

jσ

†

z

hhSi aiσ |a 0 ii

jσ

hhS

hhS

†

−σ

ai−σ |a 0 ii

i

jσ

hhS

−σ z

|Sj ii

i

z ii

hhSiz aiσ |Sj

hhS

−σ

z ii

ai−σ |Sj

i

−σ σ0

|Sj ii

hhS

i

σ0 ii

hhSiz aiσ |Sj

hhS

−σ

σ0 ii

ai−σ |Sj

i

S ii

jσ0 j

†

z ii

S

jσ0 j

−σ †

z ii

|a 0 Sj

i

jσ

†

z

z ii

hhSi aiσ |a 0 Sj

jσ

hhS

hhS

†

−σ

z ii

ai−σ |a 0 Sj

i

jσ

hhaiσ |a

S ii

j−σ0 j

†

σ0 ii

S

j−σ0 j

0

−σ †

|a

hhS

S σ ii

i

j−σ0 j

†

hhSiz aiσ |a

S σ ii

j−σ0 j

0

†

−σ

ai−σ |a

hhS

S σ ii

i

j−σ0 j

hhSiz |a

.

(28)

However, to make the problem more easily tractable, we will consider below the

shortest algebra of the relevant operators (akσ , a†kσ , bkσ , b†kσ ). However, this choice

requires a separate treatment of the spin dynamics.

Here we reproduce very briefly the description of the spin dynamics of the s–d

model for the sake of self-contained formulation. The spin quasiparticle dynamics

of the s–d model was considered in detail in papers.39,40,92 We consider the doubletime thermal GF of localized spins88 which is defined as

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A. L. Kuzemsky

−

−

G +− (k; t − t0 ) = hhSk+ (t), S−k

(t0 )ii = −iθ(t − t0 )h[Sk+ (t), S−k

(t0 )]− i

Z +∞

= 1/2π

dω exp(−iωt)G +− (k; ω) .

(29)

−∞

The next step is to write down the equation of motion for the GF. To describe

self-consistently the spin dynamics of the s–d model, one should take into account

the full algebra of relevant operators of the suitable “spin modes” which are appropriate when the goal is to describe self-consistently the quasiparticle spectra of

two interacting subsystems. We used the following generalized matrix GF of the

form39,40,92 :

!

−

−

hhSk+ |S−k

ii hhSk+ |σ−k

ii

ˆ ω) .

= G(k;

(30)

−

−

hhσk+ |S−k

ii hhσk+ |σ−k

ii

ˆ ω). By differentiation of the

Let us consider the equation of motion for the GF G(k;

+

0

GF hhSk (t)|B(t )ii with respect to the first time, t, we find

(

)

2N −1/2 hS0z i

+

ωhhSk |Biiω =

0

+

I X +

z

hhSk−q (a†p↑ ap+q↑ − a†p↓ ap+q↓ ) − 2Sk−q

a†p↑ ap+q↓ |Biiω

N pq

+ N −1/2

X

+

z

Jq hh(Sqz Sk−q

− Sk−q

Sq+ )|Biiω

(31)

q

where

B=

(

−

S−k

−

σ−k

)

.

Let us introduce by definition irreducible (ir) operators as

(Sqz )ir = Sqz − hS0z iδq,0 ;

(a†p+qσ apσ )ir = a†p+qσ apσ − ha†pσ apσ iδq,0

(32)

+

z

((Sqz )ir Sk−q

− (Sk−q

)ir Sq+ )ir

+

z

= ((Sqz )ir Sk−q

− (Sk−q

)ir Sq+ ) − (φq − φk−q )Sk+ .

(33)

From the condition (12)

+

−

z

h[((Sqz )ir Sk−q

− (Sk−q

)ir Sq+ − (φq − φk−q )Sk+ ), S−k

]− i = 0

one can find

φq =

2Kqzz + Kq−+

2hS0z i

Kqzz = h(Sqz )ir (Sqz )ir i ;

(34)

−

Kq−+ = hS−q

Sq+ i .

(35)

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Bound and Scattering States in Magnetic Materials

3241

Using the definition of the mass operator Eq. (17) the equation of motion, Eq. (31),

can be exactly transformed to the Dyson equation, Eq. (18)

ˆ Gˆ .

Gˆ = Gˆ0 + Gˆ0 M

(36)

ˆ has been reduced to that of Gˆ0 and M

ˆ.

Hence, the determination of the full GF G

The GF matrix G0 in the generalized mean field approximation reads

!

−1 1/2

s

I

N

Ω

Ω

N

χ

2

2

0

(37)

Gˆ0 = R−1

Ω2 N χs0

−Ω1 N χs0

where

R = Ω1 + Ω2 IN 1/2 χs0 .

(38)

The diagonal matrix elements G011 read

−

hhSk+ |S−k

ii0 =

2Sz

Ω1 + 2I 2 Sz χs0 (k, ω)

(39)

where

Ω1 = ω −

×

hS0z i

(J0 − Jk ) − N −1/2

N 1/2

X

2Kqzz + Kq−+

− I(n↑ − n↓ )

(Jq − Jq−k )

2hS0z i

q

2hS0z iI

N

X (fp+k↓ − fp↑ )

.

χs0 (k, ω) = N −1

s

ωp,k

p

Ω2 =

(40)

(41)

(42)

Here the notation was used

s

ωp,k

= (ω + p − p+k − ∆I )

∆I = 2ISz

X

1 X †

1 X

nσ =

haqσ aqσ i =

fqσ =

(exp(βε(qσ)) + 1)−1

N q

N q

q

(43)

ε(qσ) = q − zσ ISz

X

n

¯=

(n↑ + n↓ ) ; 0 ≤ n

¯≤2

Sz = N −1/2 hS0z i .

We assume then that the local exchange parameter I = 0. In this limiting case we

have

2Sz

−

.

(44)

hhSk+ |S−k

ii0 =

P

1

ω − Sz (J0 − Jk ) − 2N Sz q (Jq − Jq−k )(2Kqzz + Kq−+ )

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A. L. Kuzemsky

The spectrum of quasiparticle excitations of localized spins without damping follows

from the poles of the generalized mean-field GF (44)

ω(k) = Sz (J0 − Jk ) +

1 X

(Jq − Jq−k )(2Kqzz + Kq−+ ) .

2N Sz q

(45)

It is seen that due to the correct definition of generalized mean fields we get the

result for the localized spin Heisenberg subsystem which includes both the simplest

spin-wave result and the result of Tyablikov decoupling as limiting cases. In the

hydrodynamic limit k → 0, ω → 0 it leads to the dispersion law ω(k) = Dk 2 .

The exchange integral Jk can be written in the following way:

X

~ i )J(|R

~ i |) .

Jk =

exp (−i~k R

(46)

i

The expansion in small ~k gives92

−

hhSk+ |S−k

ii0 =

ω(k → 0) =

2Sz

ω − ω(k)

1 X

Sz (J0 − Jk ) +

(Jq − Jq−k )(2Kqzz + Kq−+ )

2N Sz q

!

' Dk 2

!

N X

Sz

zz

−+

η0 +

ηq (2Kq + Kq ) k 2

2

2Sz2 q

=

ηq =

(47)

X

~ i )2 J(|R

~ i |) exp (−i~

~ i) .

(~k R

qR

i

It is easy to analyze the quasiparticle spectra of the (s–d) model in the case of

nonzero coupling I. The full generalized mean field GFs can be rewritten as

−

hhSk+ |S−k

ii0

=

ω − Im − Sz (J0 − Jk ) −

1

2N Sz

2Sz

−+

s

zz

2

q (Jq − Jq−k )(2Kq + Kq ) + 2I Sz χ0 (k, ω)

P

−

hhσk+ |σ−k

ii0 =

(48)

χs0 (k, ω)

.

1 − Ieff (ω)χs0 (k, ω)

(49)

Here the notation was used

Ieff =

2I 2 Sz

;

ω − Im

m = (n↑ − n↓ ) .

The precise significance of this description of spin quasiparticle dynamics appears

in the next sections.

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Bound and Scattering States in Magnetic Materials

3243

5. Charge Dynamics of the s–d Model. Scattering Regime

In order to discuss the charge quasiparticle dynamics of the s–d model, we can

use the whole development in Sec. 3. The concept of a magnetic polaron requires

that we should have also precise knowledge about the scattering charge states.

By contrasting the bound and scattering state regime, the properties of itinerant

charge carriers and their quasiparticle many-body dynamics can be substantially

clarified. We consider again the double-time thermal GF of charge operators88 which

is defined as

gkσ (t − t0 ) = hhakσ (t), a†kσ (t0 )ii = −iθ(t − t0 )h[akσ (t), a†kσ (t0 )]+ i

Z +∞

= 1/2π

dω exp(−iωt)gkσ (ω) .

(50)

−∞

To describe the quasiparticle charge dynamics or dynamics of carriers of the s–d

model self-consistently, we should consider the equation of motion for the GF g:

ωhhakσ |a†kσ iiω = 1 + k hhakσ |a†kσ iiω

X

−σ

z

− IN −1/2

aq+k−σ + zσ S−q

aq+kσ )|a†kσ iiω

hh(S−q

q

= IN −1/2 hhbkσ |a†kσ iiω .

(51)

Let us introduce by definition irreducible (ir) spin operators as

(Sqz )ir = Sqz − hS0z iδq,0

(Sqσ )ir = Sqσ − hS0σ iδq,0 = Sqσ .

(52)

By this definition we suppose that there is a long-range magnetic order in the system

under consideration with the order parameter hS0z i. The irreducible operator for the

transversal spin components coincides with the initial operator.

Equivalently, one can write down by definition irreducible GFs:

−σ

−σ

(ir hhS−q

aq+k−σ |a†kσ iiω ) = hhS−q

aq+k−σ |a†kσ iiω

z

z

(ir hhS−q

aq+kσ |a†kσ iiω ) = hhS−q

aq+kσ |a†kσ iiω

(53)

− hS0z iδq,0 hhakσ |a†kσ iiω .

Then the equation of motion for the GF gkσ (ω) can be exactly transformed to the

following form:

(ω − ε(kσ))hhakσ |a†kσ iiω + IN −1/2 hhCkσ |a†kσ ii = 1 .

(54)

Here the notation was used

Ckσ = bir

kσ =

X

q

−σ

z ir

(S−q

aq+k−σ + zσ (S−q

) aq+kσ ) .

(55)

Following the IGF strategy we should perform the differentiation of the higher-order

GFs on the second time t0 and introduce the irreducible GFs (operators) for the

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A. L. Kuzemsky

“right” side. Using this approach the equation of motion, Eq. (34), can be exactly

transformed into the Dyson equation Eq. (18)

0

0

gkσ (ω) = gkσ

(ω) + gkσ

(ω)Mkσ (ω)gkσ (ω)

(56)

0

gkσ

(ω) = hhakσ |a†kσ ii0 = (ω − ε(kσ))−1 .

(57)

where

The mean-field GF Eq. (57) contains all the mean-field renormalizations or elastic

scattering corrections. The inelastic scattering corrections, according to Eq. (56),

are separated to the mass operator Mkσ (ω). Here the mass operator has the

following exact representation (scattering regime):

e−m

Mkσ (ω) = Mkσ

(ω)

=

I 2 X (ir)

−σ

(ir),p

(( hhS−q

ak+q−σ |Ssσ a+

)

k+s−σ ii

N qs

z

(ir),p

+ ((ir) hhS−q

ak+qσ |Ssz a+

)) .

k+sσ ii

(58)

To calculate the mass operator Mkσ (ω), we express the GF in terms of the correlation functions. In order to calculate the mass operator self-consistently, we shall

use approximation of two interacting modes for M e−m . Then the corresponding

expression can be written as

Z

dω1 dω2

I2 X

e−m

F1 (ω1 , ω2 )

Mkσ

(ω) =

N q

ω − ω1 − ω2

−1

−1

σ

Im gk+q,−σ (ω2 )

ImhhS−q

|Sq−σ iiω1

π

π

−1

−1

z ir

z ir

+

Im gk+q,σ (ω2 )

Imhh(Sq ) |(S−q ) iiω1

π

π

×

(59)

where

F1 (ω1 , ω2 ) = (1 + N (ω1 ) − f (ω2 ))

N (ω(k)) = [exp(βω(k)) − 1]−1 .

Equations (56) and (59) form a closed self-consistent system of equations for onefermion GF of the carriers for the s–d model in the scattering regime. It clearly

shows that the charge quasiparticle dynamics couples intrinsically with the spin

quasiparticle dynamics in a self-consistent way.

To find explicit expressions for the mass operator, Eq. (43), we choose for the

first iteration step in its r.h.s. the following trial expressions:

1

− Im gkσ (ω) = δ(ω − ε(kσ))

π

(60)

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Bound and Scattering States in Magnetic Materials

−1

−σ

ImhhSqσ |S−q

ii ≈ zσ (2Sz )δ(ω − zσ ω(q)) .

π

Here ω(q) is given by the expression Eq. (45). Then we obtain

2I 2 hS0z i X fk+q,↓ + N (ω(q))

e−m

Mk↑

(ω) =

;

N 3/2 q ω − ε(k + q, ↓) − ω(q)

e−m

Mk↓

(ω) =

2I 2 hS0z i X 1 − fk−q,↑ + N (ω(q))

.

N 3/2 q ω − ε(k − q, ↑) − ω(q)

3245

(61)

(62)

This result was written for the low temperature region when one can drop the contributions from the dynamics of longitudinal spin GF. The last is essential at high

temperatures and in some special cases. The obtained formulas generalize the zerotemperature calculations of Davis and Liu89 and the approach of papers.27,90,91

The numerical calculations of the typical behaviour of the real and imaginary

parts of the self-energy in generalized Born approximation were carried out in

Refs. 28, 30.

6. Charge Quasiparticle Dynamics of the s−d Model. Bound

State Regime

In this section, we further discuss the spectrum of charge carrier excitations in the

s–d model and describe bound state regime. As previously, consider the double-time

thermal GF of charge operators hhakσ (t), a†kσ (t0 )ii. The next step is to write down

the equation of motion for the GF g:

(ω − ε(kσ))hhakσ |a†kσ iiω + IN −1/2 hhCkσ |a†kσ iiω = 1 .

(63)

We also have

†

†

(ω − ε(kσ))hhakσ |Ckσ

iiω + IN −1/2 hhCkσ |Ckσ

iiω = 0 .

(64)

It follows from Eqs. (63) and (64) that to take into account both the regimes,

scattering and bound state, properly, we should treat the operators akσ , a†kσ and

†

Ckσ , Ckσ

on the equal footing. That means that one should consider the new relevant

akσ

operator, a kind of “spinor” C

(“relevant degrees of freedom”) to construct a

kσ

suitable Green function. Thus, according to the IGF strategy, to describe the bound

state regime properly, contrary to the scattering regime, one should consider the

generalized matrix GF of the form

!

†

hhakσ |a†kσ iiω

hhakσ |Ckσ

iiω

ˆ ω) .

= G(k;

(65)

†

hhCkσ |a†kσ iiω hhCkσ |Ckσ

iiω

Equivalently, we can do the calculations in the Wannier representation with the

matrix of the form

!

†

hhaiσ |a†jσ ii hhaiσ |Cjσ

ii

ˆ

= G(ij;

ω) .

(66)

†

ii

hhCiσ |a†jσ ii hhCiσ |Cjσ

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A. L. Kuzemsky

The form of Eq. (66) is more convenient for considering the effects of disorder. Let

ˆ ω). To write down the

us consider now the equation of motion for the GF G(k;

ˆ ω), we need auxiliary

equation of motion for the Fourier transform of the GF G(k;

equations of motion for the following GFs of the form

−σ

(ω − ε(k + q − σ))hhS−q

ak+q−σ |a†kσ iiω

−σ

= −IN −1/2 hhS−q

Ck+q−σ |a†kσ iiω

X

−σ

z

− zσ N −1/2

Jp hh(S−(p+q)

Spz − Sp−σ S−(p+q)

)aq+k−σ |a†kσ iiω

p

= −IN −1/2

X

p

− zσ N −1/2

−σ

σ

z ir

hhS−q

(S−p

ap+k+qσ + z−σ (S−p

) ap+k+q−σ )|a†kσ iiω

X

p

−σ

z

Jp hh(S−(p+q)

Spz − Sp−σ S−(p+q)

)aq+k−σ |a†kσ iiω .

(67)

To separate the elastic and inelastic scattering corrections, it is convenient to introduce by definition the following set of irreducible operators:

−σ ir

−σ

−σ

σ

σ

(S−p

S−q

) = S−p

S−q

− hSqσ S−q

iδ−q,p

−σ

−σ

z

z

(S−(p+q)

Spz − Sp−σ S−(p+q)

)ir = (S−(p+q)

Spz − Sp−σ S−(p+q)

)

− (hS0z i(δp,0 − δp,−q )

(68)

−σ

+ (φ−p − φ−(p+q) ))S−q

).

This is the standard way of introducing the “irreducible” parts of operators or

GFs.87 However, we are interested here in describing the bound electron-magnon

states correctly. Thus, the definition of the relevant generalized mean field is more

tricky for this case. It is important to note that before introducing the irreducible

−σ

parts, Eq. (68), one has to extract from the GF hhS−q

Ck+q−σ |a†kσ ii the terms pro−σ

portional to the initial GF hhS−q

ak+q−σ |a†kσ ii. That means that we should project

the higher-order GF onto the initial one.87 This projection should be performed

using the spin commutation relations:

−σ

−σ

z

;

[S−q

, S−p

] = zσ N −1/2 S−(q+p)

−σ

σ

z

[S−q

, S−p

] = z−σ 2N −1/2 S−(q+p)

.

In other words, this procedure introduces effectively the spin-operator ordering rule

into the calculations. Roughly speaking, we should construct the relevant mean field

not for spin or electron alone, but for the complex object, the “spin-electron”, or

−σ

for the operator (S−q

ak+q−σ ). This is the crucial point of the whole treatment,

which leads to the correct definition of the generalized mean field in which the free

magnetic polaron will propagate. We have then

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Bound and Scattering States in Magnetic Materials

3247

−σ z

−σ

hhS−q

S−p ak+q+p−σ |a†kσ iiω = zσ N −1/2 hhS−(q+p)

ak+q+p−σ |a†kσ iiω

−σ

z

ak+q+p−σ |a†kσ iiω

+ hhS−p

S−q

(69)

−σ

z

z ir −σ

hhS−p

S−q

ak+q+p−σ |a†kσ iiω = hh(S−p

) S−q ak+q+p−σ |a†kσ iiω

−σ

+ hS0z iδp,0 hhS−q

ak+q−σ |a†kσ iiω

(70)

−σ σ

−σ σ

hhS−q

S−p ak+q+pσ |a†kσ iiω = hh(S−q

S−p ak+q+pσ )ir |a†kσ iiω

−σ σ

+ hS−q

Sq iδp,−q hhakσ |a†kσ ii

(71)

−σ

z

hh(S−(p+q)

Spz − Sp−σ S−(p+q)

)ak+q−σ |a†kσ iiω

−σ

z

= hh(S−(p+q)

(Spz )ir − Sp−σ (S−(p+q)

)ir )ak+q−σ |a†kσ iiω

−σ

+ hS0z i(δp,0 − δp,−q )hhS−q

ak+q−σ |a†kσ iiω .

(72)

−σ

Finally, by differentiation of the GF hhS−q

ak+q−σ (t), a†kσ (0)ii with respect to the

first time, t, and using the definition of the irreducible parts, Eqs. (69)–(72), the

equation of motion, Eq. (67), can be exactly transformed to the following form:

−σ

(ω + zσ ω(q) − ε(k + q − σ))hhS−q

ak+q−σ |a†kσ iiω

−σ σ

+ IN −1/2 hS−q

Sq ihhakσ |a†kσ iiω

X

−σ

= IN −1/2

hhS−p

ak+p−σ |a†kσ iiω + hhAq |a†kσ iiω

(73)

p

where

Aq = −IN −1/2

X

p

− zσ N −1/2

−σ −σ

z ir −σ

{(S−q

S−p ak+q+pσ )ir + z−σ (S−p

) S−q ak+q+p−σ }

X

p

−σ

z

(Spz )ir − Sp−σ (Sq+p

)ir )ir ak+q−σ

Jp (S−(p+q)

−σ

= −IN −1/2 Ck+q−σ S−q

X

−σ

z

− zσ N −1/2

(Spz )ir − Sp−σ (Sq+p

)ir )ir ak+q−σ .

Jp (S−(p+q)

p

It is easy to see that

(74)

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A. L. Kuzemsky

−σ

hhS−q

ak+q−σ |a†kσ iiω + IN −1/2

= IN −1/2

+

−σ σ

hS−q

Sq i

hhakσ |a†kσ iiω

(ω + zσ ω(q) − ε(k + q − σ))

X

1

−σ

hhS−p

ak+p−σ |a†kσ iiω

(ω + zσ ω(q) − ε(k + q − σ)) p

1

hhAq |a†kσ iiω .

(ω + zσ ω(q) − ε(k + q − σ))

(75)

After summation with respect to q we find

(

)

−σ σ

X

hS−q

Sq i

−1/2

IN

hhakσ |a†kσ iiω

(ω

+

z

ω(q)

−

ε(k

+

q

−

σ))

σ

q

(

+

=

1 − IN

−1

X

q

1

(ω + zσ ω(q) − ε(k + q − σ))

)

X

p

−σ

hhS−p

ak+p−σ |a†kσ iiω

1

hhAq |a†kσ iiω .

(ω + zσ ω(q) − ε(k + q − σ))

X

q

Then Eq. (75) can be exactly rewritten in the following form:

X

−σ

hhS−p

ak+p−σ |a†kσ iiω

(76)

q

(

= − IN −1/2

+

X

q

X

q

−σ σ

hS−q

Sq i

(1 − IΛkσ (ω))(ω + zσ ω(q) − ε(k + q − σ))

)

hhakσ |a†kσ iiω

1

hhAq |a†kσ iiω

(1 − IΛkσ (ω))(ω + zσ ω(q) − ε(k + q − σ))

(77)

where

Λkσ (ω) =

1 X

1

.

N q (ω + zσ ω(q) − ε(k + q − σ))

(78)

ˆ ω) Eq. (65) it is

To write down the equation of motion for the matrix GF G(k;

necessary to return to the operators Ckσ . We find

−σ σ

X

hS−q

Sq i

−1/2

IN

(1 − IΛkσ (ω))(ω + zσ ω(q) − ε(k + q − σ))

q

z ir

h(S−q

) (Sqz )ir i

+

hhakσ |a†kσ iiω + hhCkσ |a†kσ iiω

ω − ε(k + qσ)

X

hhAq |a†kσ iiω

hhBq |a†kσ iiω

=

+

(1 − IΛkσ (ω))(ω + zσ ω(q) − ε(k + q − σ)) ω − ε(k + qσ)

q

(79)

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02639

Bound and Scattering States in Magnetic Materials

IN −1/2

X

q

3249

−σ σ

hS−q

Sq i

(1 − IΛkσ (ω))(ω + zσ ω(q) − ε(k + q − σ))

z ir

h(S−q

) (Sqz )ir i

†

+

hhakσ |Ckσ

iiω

ω − ε(k + qσ)

−σ σ

X

hS−q

Sq i

†

+ hhCkσ |Ckσ

iiω =

(1

−

IΛ

(ω))(ω

+

z

ω(q)

− ε(k + q − σ))

kσ

σ

q

+

+

z ir

h(S−q

) (Sqz )ir i

ω − ε(k + qσ)

X

Bq = −IN −1/2

X

q

†

†

hhAq |Ckσ

iiω

hhBq |Ckσ

iiω

+

(1 − IΛkσ (ω))(ω + zσ ω(q) − ε(k + q − σ)) ω − ε(k + qσ)

(80)

where

p

z

z

z ir −σ

[(S−q

S−p

ak+q+pσ )ir + zσ (S−q

) S−p ak+q+p−σ ]

z ir

= −zσ IN −1/2 (S−q

) Ck+qσ .

(81)

The irreducible operators Eq. (68), Eqs. (69)–(72) have been introduced in such a

way that the the operators Aq and Bq satisfy the conditions

†

]+ i = 0

h[Aq , a†kσ ]+ i = h[Aq , Ckσ

†

]+ i = 0 .

h[Bq , a†kσ ]+ i = h[Bq , Ckσ

(82)

The equations of motion, Eqs. (79) and (80) can be rewritten in the following form:

IN −1/2 χbkσ (ω)hhakσ |a†kσ iiω + hhCkσ |a†kσ iiω

X

hhAq |a†kσ iiω

=

(1 − IΛkσ (ω))(ω + zσ ω(q) − ε(k + q − σ))

q

(1 + IΛkσ (ω))hhBq |a†kσ iiω

+

(1 − IΛkσ (ω))(ω − ε(k + qσ))

(83)

†

†

IN −1/2 χbkσ (ω)hhakσ |Ckσ

iiω + hhCkσ |Ckσ

iiω

†

X

hhAq |Ckσ

iiω

=

(1

−

IΛ

(ω))(ω

+

z

ω(q)

− ε(k + q − σ))

kσ

σ

q

+

†

(1 + IΛkσ (ω))hhBq |Ckσ

iiω

(1 − IΛkσ (ω))(ω − ε(k + qσ))

(84)

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02639

A. L. Kuzemsky

×

X

q

†

hhAq |Ckσ

iiω

(1 − IΛkσ (ω))(ω + zσ ω(q) − ε(k + q − σ))

†

(1 + IΛkσ (ω))hhBq |Ckσ

iiω

+

(1 − IΛkσ (ω))(ω − ε(k + qσ))

where

χbkσ (ω) =

X

q

+

−σ σ

hS−q

Sq i

(1 − IΛkσ (ω))(ω + zσ ω(q) − ε(k + q − σ))

z ir

(1 + IΛkσ (ω))h(S−q

) (Sqz )ir i

(1 − IΛkσ (ω))(ω − ε(k + qσ))

.

(85)

Here χbkσ (ω) plays the role of the generalized “susceptibility” of the spin-electron

bound states instead of the electron susceptibility χs0 (k, ω) in the scattering-state

regime Eq. (40) (see also Refs. 39, 40). Analogously, one can write the equation for

†

the GF hhCkσ |Ckσ

ii.

Now we are ready to write down the equation of motion for the matrix GF

ˆ ω), Eq. (65), after differentiation with respect to the first time, t. Using the

G(k;

equations of motion (80), (83), (84) and (63), we find

X

ˆ G(k;

ˆ ω) = Iˆ +

ˆ D(p;

ˆ ω)

Ω

Φ(p)

(86)

p

where

ˆ=

Ω

ˆ ω) =

D(p;

ω − ε(kσ)

IN 1/2

IN 1/2 χbkσ (ω)

1

!

hhAp |a†kσ iiω

†

hhAp |Ckσ

iiω

hhBp |a†kσ iiω

†

hhBp |Ckσ

iiω

with the notation

,

!

Iˆ =

,

1

0

χbkσ (ω)

0

ˆ

Φ(p) = 1

b

ωk,p

0

!

b

ωk,q

= (1 − IΛkσ (ω))(ω + zσ ω(q) − ε(k + q − σ))

Ωk,q =

(1 − IΛkσ (ω))

(ω − ε(k + qσ)) .

(1 + IΛkσ (ω))

(87)

0

1

Ωk,p

(88)

(89)

(90)

ˆ ω) in Eq. (86), we differentiate its r.h.s. with

To calculate the higher order GFs D(p;

respect to the second-time variable (t0 ). After introducing the irreducible parts as

discussed above, but this time for the “right” operators, and combining both (the

first- and second-time differentiated) equations of motion, we get the “exact” (no

approximation has been made till now) “scattering” equation

ˆ ω) = G

ˆ 0 (k; ω) + G

ˆ 0 (k; ω)Pˆ G

ˆ 0 (k; ω) .

G(k;

(91)

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Bound and Scattering States in Magnetic Materials

3251

Here the generalized mean-field GF was defined as

ˆ 0 (k; ω) = Ω−1 Iˆ .

G

k,p

(92)

Note that it is possible to arrive at Eq. (91) using the symmetry properties too. We

have

X

ˆ†Ω

ˆ † = Iˆ† +

ˆ †Φ

ˆ † (q)

G

D

q

ˆ = Iˆ† (Ω

ˆ † )−1 +

G

X

ˆ † (q)(Ω

ˆ † )−1

ˆ †Φ

D

q

ˆ† =

ΩD

X

ˆ

ˆ† = G

ˆ = (Ω

ˆ −1 I)

G

ˆ Pˆ (pq)

Φ(p)

p

ˆ = (Ω

ˆ −1 I)

ˆ † + (Ω

ˆ −1 I)

ˆ

G

X

ˆ Pˆ (pq)Φ

ˆ † (q)(Iˆ−1 )† (Ω

ˆ −1 I)

ˆ†

Iˆ−1 Φ(p)

pq

Pˆ = Iˆ−1

Pˆ (pq) =

(

X

)

ˆ Pˆ (pq)Φ

ˆ † (q) Iˆ−1

Φ(p)

pq

hhAp |A†q ii

hhAp |Bq† ii

hhBp |A†q ii

hhBp |Bq† ii

!

(93)

.

(94)

We shall now consider the magnetic polaron state in the generalized mean field

approximation and estimate the binding energy of the magnetic polaron.

7. Magnetic Polaron in Generalized Mean Field

From the definition, Eq. (92), the generalized mean-field GF matrix reads

!

†

†

0

0

hha

|a

ii

hha

|C

ii

kσ

kσ

kσ

kσ

ˆ 0 (k; ω) =

G

†

hhCkσ |a†kσ ii0 hhCkσ |Ckσ

ii0

!

1

−IN −1/2 χbkσ (ω)

1

=

ˆ −IN −1/2 χb (ω) (ω − ε(kσ))χb (ω)

det Ω

kσ

(95)

kσ

where

ˆ = ω − ε(kσ) − I 2 N −1 χb (ω) .

det Ω

kσ

22

Let us write down explicitly the diagonal matrix elements G11

0 and G0

ˆ −1 = (ω − ε(kσ) − I 2 N −1 χb (ω))−1 .

hhakσ |a†kσ ii0 = (det Ω)

kσ

(96)

The corresponding GF for the scattering regime are given by Eq. (57). As it follows

from Eqs. (57) and (96) the mean-field GF hhakσ |a†kσ ii0 in the bound-state regime

has a very nontrivial structure which is quite different from the scattering-state

regime form. This was achieved by a suitable reconstruction of the generalized

November 18, 2004 13:41 WSPC/140-IJMPB

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02639

A. L. Kuzemsky

mean field and by a sophisticated redefinition of the relevant irreducible Green

functions! We have also

†

ˆ −1 (ω − ε(kσ))(ω − ε(kσ) − det Ω))

ˆ N .

hhCkσ |Ckσ

ii0 = (det Ω)

I2

(97)

It follows from Eq. (96) that the quasiparticle spectrum of the electron-magnon

bound states in the generalized mean field renormalization are determined by the

equation

Ekσ = ε(kσ) + I 2 N −1 χbkσ (Ekσ ) .

(98)

The bound polaron-like electron-magnon energy spectrum consists of two branches

for any electron spin projection. At the so-called “atomic limit” (when k = 0) and

in the limit k → 0, ω → 0 we obtain the exact analytical representation for the

single-particle GF of the form

hhakσ |a†kσ ii0 =

S − z σ Sz

S + z σ Sz

(ω + IS)−1 +

(ω − I(S + 1))−1 .

2S + 1

2S + 1

(99)

hS z i

0

Here the notation S and Sz = √N

means the spin-value and magnetization, respectively. This result was derived previously in paper.60

However, our approach is the closest to the seminal paper of Shastry and

Mattis,74 where the Green function treatment of the magnetic polaron problem

was formulated for zero temperature. Our generalized mean-field solution is reduced

exactly to the Shastry–Mattis result if we put in our expression for the spectrum,

Eq. (97), the temperature T = 0

hhakσ |a†kσ ii0 |T =0

=

Λkσ (ω)

ω − ε(kσ) − δσ↓ 2I S

(1 − IΛkσ (ω))

2

−1

.

(100)

We can see that the magnetic polaron states are formed for antiferromagnetic

s–d coupling (I < 0) only when there is a lowering of the band of the uncoupled

itinerant charge carriers due to the effective attraction of the carrier and magnon.

The derivation of Eq. (100) was carried out for arbitrary interrelations between

the s–d model parameters. Let us consider now the two limiting cases where analytical calculations are possible.

(i) a wide-band semiconductor (|I|S W )

Ek↓ ' k + I

+

S(S + Sz + 1) + Sz (S − Sz + 1)

2S

−

(−I) X (k−q − k + 2I(S − Sz )) hSq+ S−q i

;

N

(k−q − k + 2ISz )

2S

q

(ii) a narrow-band semiconductor (|I|S W )

(101)

November 18, 2004 13:41 WSPC/140-IJMPB

02639

Bound and Scattering States in Magnetic Materials

Ek↓ ' I(S + 1) +

+

3253

2(S + 1)(S + Sz )

k

(2S + 1)(S + Sz + 1)

−

1 X (k−q − k ) hSq+ S−q i

.

N q (2S + 1) (S + Sz + 1)

(102)

In the above formulae the correlation function of the longitudinal spin components

Kqzz was omitted for the sake of simplicity. Here W is the bandwidth in the limit

I = 0.

Let us now consider in more detail the low-temperature spin-wave limit in

Eqs. (101) and (102). In that limit it is reasonable to suppose that Sz ' S. In

the spin-wave approximation we also have

−

i ' 2S(1 + N (ω(q))) .

hSq+ S−q

Thus, we obtain (c.f. Refs. 27, 60).

(i) a wide-band semiconductor (|I|S W )

1

2I 2 S X

Ek↓ ' k + IS +

N

(k − k−q + 2IS)

q

+

(−I) X

(k−q − k )

N (ω(q)) ;

N q (k−q − k − 2IS)

(ii) a narrow-band semiconductor (|I|S W )

2S

2S

(k−q − k )

1 X

Ek↓ ' I(S + 1) +

k +

N (ω(q)) .

(2S + 1)

N q (2S + 1) (2S + 1)

(103)

(104)

We shall now estimate the binding energy of the magnetic polaron bound state.

The binding energy of the magnetic polaron is convenient to define as

εB = εk↓ − Ek↓ .

(105)

This definition is quite natural and takes into account the fact that in the simple

Hartree–Fock approximation the spin-down band is given by the expression

εk↓ = k + IS .

Then the binding energy εB behaves according to the formula:

(i) a wide-band semiconductor (|I|S W )

(k−q − k )

(−I) X

εB = ε0B1 −

N (ω(q)) ;

N q (k−q − k − 2IS)

(106)

(ii) a narrow-band semiconductor (|I|S W )

2S

(k−q − k )

1 X

N (ω(q))

εB = ε0B2 −

N q (2S + 1) (2S + 1)

(107)

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02639

A. L. Kuzemsky

where

ε0B1 =

1

(2I 2 S) X

|I|S

'

|I|

N

(k−q − k − 2IS)

W

q

ε0B2 = −I +

k

' |I| .

(2S + 1)

(108)

The present consideration gives the generalization of the thermodynamic study of

the magnetic polaron. Clearly, local magnetic order lowers the state energy of the

dressed itinerant carrier, with respect to some conduction or valence band. It is

obvious that below TN of the antiferromagnet the mobility of spin polarons will be

less than of bare carriers,93 since they have to drag their polarization cloud along.

Experimental evidence for magnetic polarons in concentrated magnetic semiconductors came from optical studies of EuTe, an antiferromagnet.94 Direct measurements

of the polaron-binding energy were carried out in Ref. 95.

8. Quasiparticle Many-Body Dynamics and Damping of

Quasiparticle States

8.1. Green function picture of quasiparticles

An effective way of viewing quasiparticles, quite general and consistent, is via the

Green function scheme of many-body theory87 which we sketch below for completeness.

At sufficiently low temperatures, a few quasiparticles are excited and, therefore, this dilute quasiparticle gas is nearly a noninteracting gas in the sense that

the quasiparticles rarely collide. The success of the quasiparticle concept in an interacting many-body system is particularly striking because of a great number of

various applications. However, the range of validity of the quasiparticle approximation, especially for strongly interacting lattice systems, was not discussed properly

in many cases. In systems like simple metals, quasiparticles constitute long-lived,

weakly interacting excitations, since their intrinsic decay rate varies as the square

of the dispersion law, thereby justifying their use as the building blocks for the

low-lying excitation spectrum.

As we have mentioned earlier, to describe a quasiparticle correctly, the Irreducible Green functions method is a very suitable and useful tool.

It is known87 that the GF is completely determined by the spectral weight

function A(ω). To explain this, let us remind that the GFs are linear combinations

of the time correlation functions

Z +∞

1

0

0

dω exp[iω(t − t0 )]AAB (ω)

(109)

FAB (t − t ) = hA(t)B(t )i =

2π −∞

Z +∞

1

FBA (t0 − t) = hB(t0 )A(t)i =

dω exp[iω(t0 − t)]ABA (ω) .

(110)

2π −∞

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Bound and Scattering States in Magnetic Materials

Here, the Fourier transforms AAB (ω) and ABA (ω) are of the form

X

†

ABA (ω) = Q−1 2π

exp(−βEn )(ψn† Bψm )(ψm

Aψn )δ(En − Em − ω)

3255

(111)

m,n

AAB = exp(−βω)ABA (−ω) .

(112)

Expressions (111) and (112) are spectral representations of the corresponding time

correlation functions. The quantities AAB and ABA are spectral densities or spectral

weight functions.

It is convenient to define

Z +∞

1

dωA(ω)

(113)

FBA (0) = hB(t)A(t)i =

2π −∞

Z +∞

1

FAB (0) = hA(t)B(t)i =

dω exp(βω)A(ω) .

(114)

2π −∞

Then, the spectral representations of the Green functions can be expressed in the

form

Gr (ω) = hhA|Biirω

Z +∞

1

dω 0

[exp(βω 0 ) − η]A(ω 0 )

=

2π −∞ ω − ω 0 + i

Ga (ω) = hhA|Biiaω

Z +∞

dω 0

1

=

[exp(βω 0 ) − η]A(ω 0 ) .

2π −∞ ω − ω 0 − i

(115)

(116)

The most important practical consequence of spectral representations for the retarded and advanced GFs is the so-called spectral theorem. The spectral theorem

can be written as

Z

1 +∞

dω exp[iω(t − t0 )][exp(βω) − η]−1 ImGAB (ω + i) (117)

hB(t0 )A(t)i = −

π −∞

1

hA(t)B(t )i = −

π

0

Z

+∞

dω exp(βω)

−∞

× exp[iω(t − t0 )][exp(βω) − η]−1 ImGAB (ω + i) .

(118)

Expressions (117) and (118) are of fundamental importance. They directly relate

the statistical averages with the Fourier transforms of the corresponding GFs. The

problem of evaluating the latter is thus reduced to finding their Fourier transforms

providing the practical usefulness of the Green functions technique.88,87

The spectral weight function reflects the microscopic structure of the system

under consideration. Its Fourier transform origination is then the density of states

that can be reached by adding or removing a particle of a given momentum and energy. Consider a system of interacting fermions as an example. For a noninteracting

November 18, 2004 13:41 WSPC/140-IJMPB

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A. L. Kuzemsky

system, the spectral weight function of the single-particle GF Gk (ω) = hhakσ ; a†kσ ii

has a simple peaked structure

Ak (ω) ∼ δ(ω − k ) .

For an interacting system, the spectral function Ak (ω) has no such a simple peaked

structure, but it obeys the following conditions:

Z

Ak (ω) ≥ 0 ;

Ak (ω)dω = h[akσ , a†kσ ]+ i = 1 .

Thus, we can see from these expressions that for a noninteracting system, the

sum rule is exhausted by a single peak. A sharply peaked spectral function for

an interacting system means a long-lived single-particle-like excitation. Thus, the

spectral weight function was established here as a physically significant attribute

of GF. The question of what is the best way of extracting it from a microscopic

theory is the main aim of the present theory.

The GF for a noninteracting system is Gk (ω) = (ω − k )−1 . For a weakly interacting Fermi system, we have Gk (ω) = (ω − k − Mk (ω))−1 where Mk (ω) is the

mass operator. Thus, for a weakly interacting system, the δ-function for Ak (ω) is

spread into a peak of finite width due to the mass operator. We have

Mk (ω ± i) = ReMk (ω) ∓ ImMk (ω) = ∆k (ω) ∓ Γk (ω) .

The single-particle GF can be written in the form

Gk (ω) = {ω − [k + ∆k (ω)] ± Γk (ω)}−1 .

(119)

In the weakly interacting case, we can thus find the energies of quasiparticles by

looking for the poles of single-particle GF (119)

ω = k + ∆k (ω) ± Γk (ω) .

The dispersion relation of a quasiparticle

(k) = k + ∆k [(k)] ± Γk [(k)]

and the lifetime 1/Γk then reflects the inter-particle interaction. It is easy to see

the connection between the width of the spectral weight function and decay rate.

We can write

Ak (ω) = (exp(βω) + 1)−1 (−i)[Gk (ω + i) − Gk (ω − i)]

= (exp(βω) + 1)−1

2Γk (ω)

.

[ω − (k + ∆k (ω))]2 + Γ2k (ω)

(120)

In other words, for this case, the corresponding propagator can be written in the

form

Gk (t) ≈ exp(−i(k)t) exp(−Γk t) .

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3257

This form shows under which conditions, the time-development of an interacting

system can be interpreted as the propagation of a quasiparticle with a reasonably

well-defined energy and a sufficiently long lifetime. To demonstrate this, we consider

the following conditions:

∆k [(k)] (k) ;

Γk [(k)] (k) .

Then we can write

Gk (ω) =

1

[ω − (k)][1 −

d∆k (ω)

dω |ω=(k) ]

+ iΓk [(k)]

(121)

where the renormalized energy of excitations is defined by

(k) = k + ∆k [(k)] .

In this case, we have, instead of (121),

"

#−1

d∆k (ω)

2Γ(k)

−1

.

Ak (ω) = [exp(β(k)) + 1]

1−

dω

(ω − (k))2 + Γ2 (k)

(k)

(122)

As a result, we find

Gk (t) = hhakσ (t); a†kσ ii

#−1

d∆k (ω)

.

= −iθ(t) exp(−i(k)t) exp(−Γ(k)t) 1 −

dω (k)

"

(123)

A widely known strategy to justify this line of reasoning is the perturbation theory.

In a strongly interacted system on a lattice with complex spectra, the concept of a

quasiparticle needs a suitable adaptation and a careful examination. It is therefore

useful to have a workable and efficient IGF method which, as we have seen, permits

one to determine and correctly separate the elastic and inelastic scattering renormalizations by a correct definition of the generalized mean field and to calculate

real quasiparticle spectra, including the damping and lifetime effects.

8.2. Damping of magnetic polaron state

We shall now calculate the damping of the magnetic polaron state due to the

inelastic scattering effects. To obtain the Dyson equation from Eq. (91), we have

to use the relation (17). Thus, we obtain the exact Dyson equation, Eq. (18),

ˆ ω) .

ˆ ω) = G

ˆ 0 (k; ω) + G

ˆ 0 (k; ω)M

ˆ kσ G(k;

G(k;

The mass operator has the following exact representation:

0

0

ˆ kσ =

M

Πkσ (ω) .

0

χbkσ (ω)

(124)

(125)

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A. L. Kuzemsky

Here the notation was used

(

)

X hhAp |A†q iip

hhAp |Bq† iip

hhBp |A†q iip

hhBp |Bq† iip

+

+

+

Πkσ (ω) =

. (126)

b ωb

b Ω

b

Ωkp Ωkq

ωkp

ωkp

Ωkp ωkq

kq

kq

pq

For the single-particle GF of itinerant carriers we have

hhakσ |a†kσ ii = {(hhakσ |a†kσ ii0 )−1 − Σkσ (ω)}−1 .

(127)

Here the self-energy operator Σkσ (ω) was defined as

Σkσ (ω) =

Πkσ (ω)

I2

.

N 1 − (χbkσ (ω))−1 Πkσ (ω)

(128)

We shall now use the exact representation, Eq. (128), to derive a suitable selfconsistent approximate expression for the self-energy. Let us consider the GFs appearing in Eq. (126). According to the spectral theorem, Eqs. (117) and (118), it is

convenient to write down the GF hhAp |A†q iip in the following form:

hhAp |A†q iip

Z +∞

Z

dω 0

1

0

[exp(βω

)

+

1]

dt exp(iω 0 t)hA†q Ap (t)ip .

=

2π −∞ ω − ω 0 + i

(129)

Then we obtain for the correlation function hA†q Ap (t)ip

hA†q Ap (t)ip =

I2 σ †

−σ

hS C

Ck+p−σ (t)S−p

(t)i

N q k+q−σ

+ ha†q+k−σ Φ†−q−σ Φ−p−σ (t)ap+k−σ (t)i .

(130)

A further insight is gained if we select a suitable relevant “trial” approximation

for the correlation function in the r.h.s. of (130). In this paper, we show that our

formulations based on the IGF method permit one to obtain an explicit approximate

expression for the mass operator in a self-consistent way. It is clear that a relevant

trial approximation for the correlation function in (130) can be chosen in various

ways. For example, a reasonable and workable one can be the following “modemode coupling approximation”which is especially suitable for a description of two

coupled subsystems. Then the correlation function hA†q Ap (t)ip could now be written

in the approximate form using the following decoupling procedure (approximate

trial solutions):

†

†

−σ

−σ

hSqσ Ck+q−σ

Ck+p−σ (t)S−p

(t)i ' δq,p hSqσ S−q

(t)i hCk+q−σ

Ck+q−σ (t)i

ha†q+k−σ Φ†−q−σ Φ−p−σ (t)ap+k−σ (t)i ' δq,p hΦ†−q−σ Φ−q−σ (t)i ha†q+k−σ aq+k−σ (t)i .

(131)

Here the notation was introduced

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Bound and Scattering States in Magnetic Materials

3259

hΦ†−q−σ Φ−q−σ (t)i

=

1 X

z ir σ

z

σ ir

Jp Jp0 h((S−p

) Sq+p − (S−(q+p)

)ir S−p

)

N 0

pp

−σ

z

ir

z

ir ir

× (S−(p

− Sp−σ

0 (t)(S−(q+p) (t)) ) i .

0 +q) (t)(Sp0 (t))

(132)

The approximation, Eq. (131), in the diagrammatic language corresponds to neglect

of the vertex correction, i.e. the correlation between the propagation of the polaron

and the magnetic excitation, and the electron and magnon, respectively. This can

be performed since we already have in our exact expression (130) the terms proportional to I 2 and J 2 . Taking into account the spectral theorem, Eqs. (117) and

(118), we obtain from Eqs. (129)–(132)

Z Z

dω1 dω2

I2

† p

F1 (ω1 , ω2 )

(133)

hhAp |Aq ii ' δq,p

N

ω − ω1 − ω2

−1

†

ImhhCk+q−σ |Ck+q−σ iiω2

π

Z Z Z

1 X

dω1 dω2 dω3

2

+ δq,p

(Jq0 − Jq−q0 )

F2 (ω1 , ω2 , ω3 )

N 0

ω − ω1 − ω2 − ω3

−1

−σ σ

ImhhS−q

|Sq iiω1

π

q

×

−1

z

ir

z ir

Imhh(S−q

0 ) |(Sq 0 ) iiω1

π

×

−1

Imhhak+q−σ |a†k+q−σ iiω3

π

hhBp |Bq† iip '

−1

−σ

σ

ImhhS−(q−q

0 ) |Sq−q 0 iiω2

π

Z Z

dω1 dω2

I2

δq,p

F1 (ω1 , ω2 )

N

ω − ω1 − ω2

−1

−1

†

z ir

Imhh(S−q

) |(Sqz )ir iiω1

ImhhCk+qσ |Ck+qσ

iiω2

(134)

×

π

π

where

F1 (ω1 , ω2 ) = (1 + N (ω1 ) − f (ω2 ))

(135)

F2 (ω1 , ω2 , ω3 ) = (1 + N (ω1 ))(1 + N (ω2 ) − f (ω3 )) − N (ω2 )f (ω3 )

= (1 + N (ω1 ))(1 + N (ω2 )) − (1 + N (ω1 ) + N (ω2 ))f (ω2 ) .

(136)

The functions F1 (ω1 , ω2 ), Eq. (136), and F2 (ω1 , ω2 , ω3 ), Eq. (135), represent clearly

the inelastic scattering of bosons and fermions. For estimation of the damping effects

it is reasonably to accept that

hhAp |Bq† iip ' hhBp |A†q iip ' 0 .

(137)

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A. L. Kuzemsky

We have then

Πkσ '

X

hhBp |Bq† iip

hhAp |A†q iip

+

b

b

Ωkp Ωkq

ωkp ωkq

!

X

hhBq |Bq† iip

hhAq |A†q iip

+

b

2

(Ωkq )2

(ωkq )

!

qp

'

q

.

(138)

We can see that there are two distinct contributions to the self-energy. Putting

together formulae (133)–(138), we arrive at the following formulae for both the

contributions

Z Z

dω1 dω2

I2 X

F1 (ω1 , ω2 )

ΠIkσ =

N q

ω − ω1 − ω2

−1

†

ImhhC

|C

ii

k+q−σ

k+q−σ ω2

b )2

π

(ωkq

−1

−1

1

†

z ir

z ir

Imhh(S

)

|(S

)

ii

ImhhC

|C

ii

+

ω

k+qσ

ω

1

2

−q

q

k+qσ

(Ωkq )2 π

π

×

1

−1

−σ σ

ImhhS−q

|Sq iiω1

π

(139)

ΠJkσ =

Z Z Z

1 X

dω1 dω2 dω3

(Jq0 − Jq−q0 )2

N 0

ω − ω1 − ω2 − ω3

−1

z

ir

z ir

Imhh(S

)

|(S

)

ii

ω1

−q 0

q0

b )2

π

(ωkq

−1

−1

†

−σ

σ

×

ii

|S

ImhhS−(q−q

Imhha

|a

ii

0

0)

ω2

k+q−σ k+q−σ ω3 .

q−q

π

π

× F2 (ω1 , ω2 , ω3 )

1

(140)

Equations (124), (125), (139), and (140) constitute a closed self-consistent system

of equations for the single-electron GF of the s–d model in the bound state regime.

This system of equations is much more complicated than the corresponding system

of equations for the scattering states. We can see that to the extent that the spin

and fermion degrees of freedom can be factorized as in Eq. (131), the self-energy

operator can be expressed in terms of the initial GFs self-consistently. It is clear

that this representation does not depend on any assumption about the explicit form

of the spin and fermion GFs in the r.h.s. of Eqs. (139) and (140).

Let us first consider the so-called “static” limit. The thorough discussion of this

approximation was carried out in Ref. 27. We just show below that a more general

form of this approximation follows directly from our formulae. The contributions

of the GFs, Eqs. (133) and (134), are then

Z Z

I2

dω1 dω2

† p

F1 (ω1 , ω2 )

(141)

hhAp |Aq ii ' δq,p

N

ω − ω1 − ω2

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Bound and Scattering States in Magnetic Materials

3261

−1

†

ImhhCk+q−σ |Ck+q−σ iiω2

π

Z Z

1 X

dω1 dω2

2

z ir

z

ir

F1 (ω1 , ω2 )

+ δq,p

(Jq0 − Jq−q0 ) h(Sq0 ) (S−q0 ) i

N 0

ω − ω1 − ω2

−1

−σ σ

ImhhS−q

|Sq iiω1

π

q

×

−1

−σ

σ

ImhhS−(q−q

0 ) |Sq−q 0 iiω1

π

hhBp |Bq† iip '

−1

Imhhak+q−σ |a†k+q−σ iiω2

π

Z

I2

dω1

z ir

) i

δq,p h(Sqz )ir (S−q

F1 (ω1 )

N

ω − ω1

−1

†

ImhhCk+qσ |Ck+qσ iiω1

×

π

(142)

F1 (ω1 ) = (1 − f (ω1 )) .

In the limit of low carrier concentration it is possible to drop the Fermi distribution

function in Eqs. (133)–(140). In principle, we can use, in the r.h.s. of Eqs. (135)

and (137), any workable first iteration-step form of the GF and find a solution by

iteration (see Ref. 87). It is most convenient to choose, as the first iteration step,

the following simple one-pole expressions:

−1

−σ

ImhhS−p

ak+q+p−σ |Spσ a†k+q+p−σ iiω

π

−σ σ

= hS−p

Sp iδ(ω + zσ ωp − ε(k + q + p − σ)) ,

−1

z ir

Imhh(S−p

) ak+q+pσ |(Spz )ir a†k+q+pσ iiω

π

z ir

= h(S−p

) (Spz )ir iδ(ω − ε(k + q + p − σ)) ,

−1

−σ σ

hhS−q

|Sq iiω = −zσ 2hSz iδ(ω + zσ ωq ) ,

π

−1

Imhhak+q+p−σ |a†k+q+p−σ iiω = δ(ω − ε(k + q − σ)) .

π

(143)

Using Eqs. (129)–(136) in (125) we obtain the self-consistent approximate expression for the self-energy operator (the self-consistency means that we express approximately the self-energy operator in terms of the initial GF, and, in principle,

one can obtain the required solution by a suitable iteration procedure)

−σ

hSpσ S−p

i

2I 2 hS0z i X δσ↓ + N (ωq )

Σkσ (ω) '

b

2

ω

+

z

(ω

−

ω

)

−

ε(k

+ q − p − σ)

N 3/2 qp

(ωk,q )

σ

q

p

+

z ir

h(S−p

) (Spz )ir i

ω + zσ ωq − ε(k + q + p − σ)

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A. L. Kuzemsky

Z

0

I2 X

z ir

z ir

0 (1 + N (ω )) −1

Imhh(Sq ) |(S−q ) iiω0

dω

+

N qp

(Ωk,q )2

π

×

−σ σ

z ir

hS−p

Sp i

h(S−p

) (Spz )ir i

+

ω − ω 0 + zσ ωq − ε(k + q + p − σ) ω − ω 0 − ε(k + q + pσ)

.

(144)

Here we write down for brevity the contribution of the s–d interaction to the inelastic scattering only. For the spin-wave approximation and low temperatures we

get

1

(2SI)2 X

N (ωp )(1 + N (ωq ))

Σk↓ (ω) '

.

(145)

b )2 ω − (ω − ω ) − ε(k + q − p ↓)

N

(ω

q

p

k,q

qp

Using the self-energy Σkσ (ω) it is possible to calculate the energy shift ∆kσ (ω) =

Re Σkσ (ω) and damping Γkσ (ω) = −ImΣkσ (ω) of the itinerant carrier in the bound

state regime. As it follows from Eq. (145), the damping of the magnetic polaron

state arises from the combined processes of absorption and emission of magnons

with different energies (ωq − ωp ). Then the real and imaginary part of self-energy

give the effective mass, lifetime and mobility of the itinerant charge carriers

∂Σkσ

m∗

(146)

= 1 − Re

m

∂ε(kσ)

ε(kσ)=F

m 1

;

%=

ne2

τ

1

= ImΣkσ (ε(kσ))|ε(kσ)=F .

τ

(147)

9. Conclusions

In summary, we have presented an analytical approach to treating the charge quasiparticle dynamics of the spin-fermion (s–d) model which provides a basis for description of the physical properties of magnetic and diluted magnetic semiconductors.

We have investigated the mutual influence of the s–d and direct exchange effects on

interacting systems of itinerant carriers and localized spins. We set out the theory as

follows. The workable and self-consistent IGF approach to the decoupling problem

for the equation-of-motion method for double-time temperature Green functions

has been used. The main achievement of this formulation is the derivation of the

Dyson equation for double-time retarded Green functions instead of causal ones.

That formulation permits one to unify convenient analytical properties of retarded

and advanced GF and the formal solution of the Dyson equation which, in spite

of the required approximations for the self-energy, provides the correct functional

structure of single-particle GF. The main advantage of the mathematical formalism is brought out by showing how elastic scattering corrections (generalized mean

fields) and inelastic scattering effects (damping and finite lifetimes) could be selfconsistently incorporated in a general and compact manner. This approach gives a

workable scheme for definition of relevant generalized mean fields written in terms

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Bound and Scattering States in Magnetic Materials

3263

of appropriate correlators. A comparative study of real many-body dynamics of the

spin-fermion model is important to characterize the true quasiparticle excitations

and the role of magnetic correlations. It was shown that the charge and magnetic

dynamics of the spin-fermion model can be understood in terms of the combined

dynamics of itinerant carriers, and of localized spins and magnetic correlations of

various nature. The two other principal distinctive features of our calculation were,

first, the use of correct analytic definition of the relevant generalized mean fields

and, second, the explicit self-consistent calculation of the charge and spin-wave

quasiparticle spectra and their damping for the two interacting subsystems. This

analysis includes the scattering and bound state regimes that determine the essential physics. We demonstrated analytically, by contrasting the scattering and bound

state regime that the damping of magnetic polaron is affected by both the s–d and

direct exchange. Thus, the present consideration is the most complete analysis of

the scattering and bound state quasiparticle spectra of the spin-fermion model. As

it is seen, this treatment has advantages in comparison with the standard methods

of decoupling of higher order GFs within the equation-of-motion approach, namely,

the following:

At the mean-field level, the GF one obtains, is richer than that following from

the standard procedures. The generalized mean fields represent all elastic scattering

renormalizations in a compact form.

The approximations (the decoupling) are introduced at a later stage with respect

to other methods, i.e., only into the rigorously obtained self-energy.

The physical picture of elastic and inelastic scattering processes in the interacting many-particle systems is clearly seen at every stage of calculations, which is not

the case with the standard methods of decoupling.

Many results of the previous works are reproduced mathematically more simply.

The main advantage of the whole method is the possibility of a self-consistent

description of quasiparticle spectra and their damping in a unified and coherent

fashion. Thus, this picture of an interacting spin-fermion system on a lattice is far

richer and gives more possibilities for analysis of phenomena which can actually take

place. In this sense, the approach we suggest produces a more advanced physical

picture of the quasiparticle many-body dynamics. We have attempted to keep the

mathematical complexity within reasonable bounds by restricting the discussion,

whenever possible, to the minimal necessary formalization. Our main results reveal

the fundamental importance of the adequate definition of generalized mean fields

at finite temperatures which results in a deeper insight into the nature of the bound

and scattering quasiparticle states of the correlated lattice fermions and spins. The

key to understanding of the formation of magnetic polaron in magnetic semiconductors lies in the right description of the generalized mean fields for coupled spin and

charge subsystems. Consequently, it is crucial that the correct functional structure

of generalized mean fields is calculated in a closed and compact form. The essential new feature of our treatment is that it takes account the fact that the charge

carrier operators (a†kσ , akσ ) should be treated on the equal footing with the complex

November 18, 2004 13:41 WSPC/140-IJMPB

3264

02639

A. L. Kuzemsky

†

“spin-fermion” operators (Ckσ

, Ckσ ). The solution thus obtained agrees with that

obtained in the seminal paper of Shastry and Mattis,74 where an approach limited

to zero temperature was used.

Finally, we wish to emphasize a broader relevance of the results presented here

to other complex magnetic materials. The detailed consideration of the state of

itinerant charge carriers in DMS along this line will be considered separately.

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